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Metal-Sulfur Chemistry - Unusual Gold(I) Chemistry

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AurophilicvsQY

The correlation between aurophilic forces and quantum yield

Chen, J.; Mohamed, A. A.; Abdou, H. A.; Krause Bauer, J. A.; Fackler, Jr., J. P.; Bruce, A. E.; Bruce, M. R. M. “Novel Metallamacrocyclic Gold(I) Thiolate Cluster Complex: Structure and Luminescence of [Au 9(µ-dppm)4(µ-p-tc)6](PF6)3” J. Chem. Soc. Chem. Commun. 2005, 1575-1577.

Foley, Janet B.; Gay, Stanley E.; Vela, Michael J.; Foxman, Bruce M.; Bruce, Alice E. ; Bruce, Mitchell R. M. “Structure and Photochemical Isomerization of the Dinuclear Gold(I) Halide Bis(diphenylphosphanyl)ethylene Complexes: Correlation Between Quantum Yield and Aurophilicity” Eur. J. Inorg. Chem.,2007, 4946-4951.

Chen, J.; Jiang, T.; Wei, G.; Mohamed, A.A.; Homrighausen, C.; Krause Bauer, J.A.; Bruce, A.E.; Bruce, M.R.M. “Electrochemical and Chemical Oxidation of Gold(I) Thiolate Phosphine Complexes: Formation of Gold Clusters and Disulfide”, Journal of the American Chemical Society, 1999121, 9225.

Foley, J.B.; Bruce, A.E.; Bruce, M.R.M. “An Unprecedented Photochemical Cis to Trans Isomerization of Dinuclear Gold(I) Bis(diphenylphosphino)ethylene Complexes.” Journal of the American Chemical Society1995117, 9596.

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